793 research outputs found
Anomalous Lattice Response at the Mott Transition in a Quasi-2D Organic Conductor
Discontinuous changes of the lattice parameters at the Mott metal-insulator
transition are detected by high-resolution dilatometry on deuterated crystals
of the layered organic conductor -(BEDT-TTF)Cu[N(CN)]Br.
The uniaxial expansivities uncover a striking and unexpected anisotropy,
notably a zero-effect along the in-plane c-axis along which the electronic
interactions are relatively strong. A huge thermal expansion anomaly is
observed near the end-point of the first-order transition line enabling to
explore the critical behavior with very high sensitivity. The analysis yields
critical fluctuations with an exponent 0.8 0.15
at odds with the novel criticality recently proposed for these materials
[Kagawa \textit{et al.}, Nature \textbf{436}, 534 (2005)]. Our data suggest an
intricate role of the lattice degrees of freedom in the Mott transition for the
present materials.Comment: 4 pages, 4 figure
Impact of high solar zenith angles on dynamical and chemical processes in a coupled chemistry-climate model
International audienceActinic fluxes at high solar zenith angles (SZAs) are important for atmospheric chemistry, especially under twilight conditions in polar winter and spring. The results of a sensitivity experiment employing the fully coupled 3D chemistry-climate model ECHAM4.L39(DLR)/CHEM have been analysed to quantify the impact of SZAs greater than 87.5° on dynamical and chemical processes in the lower stratosphere, in particular their influence on the ozone layer. Although the actinic fluxes at SZAs larger than 87.5° are small, ozone concentrations are significantly affected because daytime photolytic ozone destruction is switched on earlier, especially the conversion of Cl2 and Cl2O2 into ClO at the end of polar night in the lower stratosphere. Comparing climatological mean ozone column values of a simulation considering SZAs up to 93° with those of the sensitivity run with SZAs confined to 87.5° total ozone is reduced by about 20% in the polar Southern Hemisphere, i.e., the ozone hole is "deeper'' if twilight conditions are considered in the model because there is 2?3 weeks more time for ozone destruction. This causes an additional cooling of the polar lower stratosphere (50 hPa) up to ?4 K with obvious consequences for chemical processes. In the Northern Hemisphere the impact of high SZAs cannot be determined on the basis of climatological mean values due to the pronounced dynamic variability of the stratosphere in winter and spring
Effects of Two Energy Scales in Weakly Dimerized Antiferromagnetic Quantum Spin Chains
By means of thermal expansion and specific heat measurements on the
high-pressure phase of (VO)PO, the effects of two energy scales of
the weakly dimerized antiferromagnetic = 1/2 Heisenberg chain are explored.
The low energy scale, given by the spin gap , is found to manifest
itself in a pronounced thermal expansion anomaly. A quantitative analysis,
employing T-DMRG calculations, shows that this feature originates from changes
in the magnetic entropy with respect to , . This term, inaccessible by specific heat, is visible only in the
weak-dimerization limit where it reflects peculiarities of the excitation
spectrum and its sensitivity to variations in .Comment: 4 pages, 4 figures now identical with finally published versio
Nature of the spin dynamics and 1/3 magnetization plateau in azurite
We present a specific heat and inelastic neutron scattering study in magnetic
fields up into the 1/3 magnetization plateau phase of the diamond chain
compound azurite Cu(CO)(OH). We establish that the
magnetization plateau is a dimer-monomer state, {\it i.e.}, consisting of a
chain of monomers, which are separated by dimers on the
diamond chain backbone. The effective spin couplings K
and K are derived from the monomer and dimer
dispersions. They are associated to microscopic couplings K,
K and a ferromagnetic K, possibly as
result of orbitals in the Cu-O bonds providing the superexchange
pathways.Comment: 5 pages, 4 figure
Inelastic Diffraction and Spectroscopy of Very Weakly Bound Clusters
We study the coherent inelastic diffraction of very weakly bound two body
clusters from a material transmission grating. We show that internal
transitions of the clusters can lead to new separate peaks in the diffraction
pattern whose angular positions determine the excitation energies. Using a
quantum mechanical approach to few body scattering theory we determine the
relative peak intensities for the diffraction of the van der Waals dimers
(D_2)_2 and H_2-D_2. Based on the results for these realistic examples we
discuss the possible applications and experimental challenges of this coherent
inelastic diffraction technique.Comment: 15 pages + 5 figures. J. Phys. B (in press
Linear sampling method for identifying cavities in a heat conductor
We consider an inverse problem of identifying the unknown cavities in a heat
conductor. Using the Neumann-to-Dirichlet map as an input data, we develop a
linear sampling type method for the heat equation. A new feature is that there
is a freedom to choose the time variable, which suggests that we have more data
than the linear sampling methods for the inverse boundary value problem
associated with EIT and inverse scattering problem with near field data
Decoherence in a Talbot Lau interferometer: the influence of molecular scattering
We study the interference of C70 fullerenes in a Talbot-Lau interferometer
with a large separation between the diffraction gratings. This permits the
observation of recurrences of the interference contrast both as a function of
the de Broglie wavelength and in dependence of the interaction with background
gases. We observe an exponential decrease of the fringe visibility with
increasing background pressure and find good quantitative agreement with the
predictions of decoherence theory. From this we extrapolate the limits of
matter wave interferometry and conclude that the influence of collisional
decoherence may be well under control in future experiments with proteins and
even larger objects.Comment: 8 pages, 5 figure
Magnetoelastic and structural properties of azurite Cu3(CO3)2(OH)2 from neutron scattering and muon spin rotation
Azurite, Cu3(CO3)2(OH)2, has been considered an ideal example of a
one-dimensional (1D) diamond chain antiferromagnet. Early studies of this
material imply the presence of an ordered antiferromagnetic phase below K while magnetization measurements have revealed a 1/3 magnetization
plateau. Until now, no corroborating neutron scattering results have been
published to confirm the ordered magnetic moment structure. We present recent
neutron diffraction results which reveal the presence of commensurate magnetic
order in azurite which coexists with significant magnetoelastic strain. The
latter of these effects may indicate the presence of spin frustration in zero
applied magnetic field. Muon spin rotation, SR, reveals an onset of
short-range order below 3K and confirms long-range order below .Comment: 5 pages, 4 figures, PHYSICAL REVIEW B 81, 140406(R) (2010
Improved simulation of isoprene oxidation chemistry with the ECHAM5/MESSy chemistry-climate model: lessons from the GABRIEL airborne field campaign
The GABRIEL airborne field measurement campaign, conducted over the Guyanas in October 2005, produced measurements of hydroxyl radical (OH) concentration which are significantly higher than can be simulated using current generation models of atmospheric chemistry. Based on the hypothesis that this "missing OH" is due to an as-yet undiscovered mechanism for recycling OH during the oxidation chain of isoprene, we determine that an OH recycling of about 40–50% (compared with 5–10% in current generation isoprene oxidation mechanisms) is necessary in order for our modelled OH to approach the lower error bounds of the OH observed during GABRIEL. Such a large amount of OH in our model leads to unrealistically low mixing ratios of isoprene. In order for our modelled isoprene mixing ratios to match those observed during the campaign, we also require that the effective rate constant for the reaction of isoprene with OH be reduced by about 50% compared with the lower bound of the range recommended by IUPAC. We show that a reasonable explanation for this lower effective rate constant could be the segregation of isoprene and OH in the mixed layer. Our modelling results are consistent with a global, annual isoprene source of about 500 Tg(C) yr<sup>&minus;1</sup>, allowing experimentally derived and established isoprene flux rates to be reconciled with global models
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